Competition of singlet and triplet recombination of radical pairs in photoreactions of carboxy benzophenones and aromatic amino acids
Author:
Affiliation:
1. International Tomography Center
2. 630090 Novosibirsk
3. Russia
4. Novosibirsk State University
Abstract
Time-resolved chemically induced dynamic nuclear polarization and transient absorption were applied to reveal the branching ratio of the singlet and triplet recombination channels in the reaction of short-lived radicals of carboxy benzophenones and the aromatic amino acids.
Funder
Russian Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2019/CP/C8CP06760K
Reference43 articles.
1. Proton-Coupled Electron Transfer from Hydrogen-Bonded Phenols to Benzophenone Triplets
2. Effect of Amino Group Charge on the Photooxidation Kinetics of Aromatic Amino Acids
3. Oxidation of Purine Nucleotides by Triplet 3,3′,4,4′-Benzophenone Tetracarboxylic Acid in Aqueous Solution: pH-Dependence
4. Modulation of the Rate of Reversible Electron Transfer in Oxidized Tryptophan and Tyrosine Containing Peptides in Acidic Aqueous Solution
5. Light-induced spin hyperpolarisation in condensed phase
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