The impact of earth-abundant metals as a replacement for Pd in cross coupling reactions-Reference-Cited by-同舟云学术

The impact of earth-abundant metals as a replacement for Pd in cross coupling reactions

Published:2024 Issue:24 Volume:15 Page:9016-9025
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Luescher Michael U.¹^ORCID,Gallou Fabrice¹^ORCID,Lipshutz Bruce H.²^ORCID

Affiliation:

1. Chemical & Analytical Development, Novartis Pharma AG, Postfach, CH-4002 Basel, Switzerland

2. Department of Chemistry & Biochemistry, University of California, Santa Barbara, CA 93106, USA

Abstract

Initial calculations of environmental footprints associated with using Ni vs Pd catalysis in a representative metal-catalyzed Suzuki–Miyaura cross-coupling reveal that the choice of ligated metal is often NOT of consequence. Rather, it is a culmination of other parameters such as medium.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00482E

Reference52 articles.

1. Recent advances in nickel catalyzed Suzuki-Miyaura cross coupling reaction via C-O& C-N bond activation

2. Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling Facilitated by a Weak Amine Base with Water as a Cosolvent

3. Advancing Base-Metal Catalysis: Development of a Screening Method for Nickel-Catalyzed Suzuki–Miyaura Reactions of Pharmaceutically Relevant Heterocycles

4. [Ni(Np^#)(η⁵-Cp)Cl]: Flexible, Sterically Bulky, Well-Defined, Highly Reactive Complex for Nickel-Catalyzed Cross-Coupling

5. Nickel-catalyzed Suzuki–Miyaura cross-couplings of aldehydes

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