Variable coordination of carbazolyl-bis(tetrazole) ligands in lanthanide chemistry
Author:
Affiliation:
1. Department of Chemistry
2. University of Victoria
3. Victoria BC V8W 2Y2
4. Canada
5. Department of Chemistry & Biochemistry
6. University of Notre Dame
7. Notre Dame
8. USA
Abstract
Lanthanide complexes of 1,8-bis(2′-isopropyltetrazo-5′-yl)-3,6-di-tert-butylcarbazolide adopt geometries that include planar, buckled and tetrazolyl-bridged tridentate, as well as bidentate, bonding modes.
Funder
Natural Sciences and Engineering Research Council of Canada
U.S. Department of Energy
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT02757A
Reference90 articles.
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3. Unusual Redox Chemistry of Ytterbium Carbazole–Bis(oxazoline) Compounds: Oxidative Coupling of Primary Phosphines by an Ytterbium Carbazole–Bis(oxazoline) Dialkyl
4. Synthesis and Reactivity of Dialkyl Lutetium Complexes Supported by a Novel Bis(phosphinimine)carbazole Pincer Ligand
5. Kinetic and Mechanistic Investigation of Metallacycle Ring Opening in an Ortho-Metalated Lutetium Aryl Complex
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