Construction of tetranuclear metallacycles based on half-sandwich Ir, Rh fragments and pyridyl-substituted ligands with different coordinate vectors-Reference-Cited by-同舟云学术

Construction of tetranuclear metallacycles based on half-sandwich Ir, Rh fragments and pyridyl-substituted ligands with different coordinate vectors

Published:2016 Issue:11 Volume:45 Page:4534-4540
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Fan Qi-Jia¹²³⁴⁵,Zhang Wen-Ying¹²³⁴⁵,Lin Yue-Jian¹²³⁴⁵,Jin Guo-Xin¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Molecular Engineering of Polymers

2. Collaborative Innovation Center of Chemistry for Energy Materials

3. Department of Chemistry

4. Fudan University

5. Shanghai 200433

Abstract

Two-step reactions of [Cp*M(μ-Cl)Cl]₂ (M = Ir, Rh), first with AgOTf and then with pyridyl-substituted ligands of different coordinate vectors, resulted in the formation of distorted tetrahedral and parallelogram type tetranuclear metallacycles.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT00171H

Reference43 articles.

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2. High-Symmetry Coordination Cages via Self-Assembly

3. Trinuclear Metallacycles: Metallatriangles and Much More

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5. Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials

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