Early dynamics of the emission of solvated electrons from nanodiamonds in water

Author:

Buchner Franziska12,Kirschbaum Thorren13,Venerosy Amélie4,Girard Hugues45,Arnault Jean-Charles45ORCID,Kiendl Benjamin2,Krueger Anke26ORCID,Larsson Karin7,Bande Annika1ORCID,Petit Tristan1ORCID,Merschjann Christoph1ORCID

Affiliation:

1. Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin, Germany

2. Institut für Organische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany

3. Freie Universität Berlin, FB Mathematik & Informatik, Artificial Intelligence for the Sciences, Arnimallee 12, D-14195 Berlin, Germany

4. CEA, LIST, Diamond Sensors Laboratory, Bâtiment 451, PC 45, 91191 Gif sur Yvette Cedex, France

5. Université Paris-Saclay, CEA, CNRS, NIMBE, 91191 Gif sur Yvette Cedex, France

6. Institute of Organic Chemistry, University of Stuttgart, Pfaffenwaldring 55, D-70569 Stuttgart, Germany

7. Uppsala University, Lägerhyddsvägen 1, 751 21, Uppsala, Sweden

Abstract

Ultrafast transient absorption on nanodiamonds reveals synergistic effects between hydrogen termination and sp2-hybridized surface reconstructions, facilitating visible-light driven electron emission.

Funder

H2020 European Research Council

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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