Selectivity of tungsten mediated dinitrogen splitting vs. proton reduction-Reference-Cited by-同舟云学术

Selectivity of tungsten mediated dinitrogen splitting vs. proton reduction

Published:2019 Issue:44 Volume:10 Page:10275-10282
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Schluschaß Bastian¹²³⁴,Abbenseth Josh¹²³⁴,Demeshko Serhiy¹²³⁴,Finger Markus¹²³⁴,Franke Alicja⁵⁶⁷⁸⁴,Herwig Christian⁹¹⁰¹¹⁴,Würtele Christian¹²³⁴,Ivanovic-Burmazovic Ivana⁵⁶⁷⁸⁴,Limberg Christian⁹¹⁰¹¹⁴^ORCID,Telser Joshua¹²¹³¹⁴¹⁵^ORCID,Schneider Sven¹²³⁴^ORCID

Affiliation:

1. Georg-August-Universität

2. Institut für Anorganische Chemie

3. 37077 Göttingen

4. Germany

5. Lehrstuhl für Bioanorganische Chemie

6. Department Chemie und Pharmazie

7. Friedrich-Alexander-Universität Erlangen

8. 91058 Erlangen

9. Institut für Chemie

10. Humboldt Universität zu Berlin

11. 12489 Berlin

12. Department of Biological, Physical and Health Sciences

13. Roosevelt University

14. Chicago

15. USA

Abstract

An N₂-bridged ditungsten complex is presented that undergoes N₂-splitting or hydrogen evolution upon protonation depending on the acid and reaction conditions. Spectroscopic, kinetic and computational results emphasize the impact of hydrogen bonding on the reaction selectivity.

Funder

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC03779A

Reference52 articles.

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2. Catalytic conversion of nitrogen to ammonia by an iron model complex

3. Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron