Higher spin states in some low-energy bis(tetramethyl-1,2-diaza-3,5-diborolyl) sandwich compounds of the first row transition metals: boraza analogues of the metallocenes-Reference-Cited by-同舟云学术

Higher spin states in some low-energy bis(tetramethyl-1,2-diaza-3,5-diborolyl) sandwich compounds of the first row transition metals: boraza analogues of the metallocenes

Published:2019 Issue:11 Volume:43 Page:4497-4505
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Chen Jianlin¹²³⁴,Feng Hao¹²³⁴,Xie Yaoming⁵⁶⁷,King R. Bruce¹²³⁴⁵^ORCID,Schaefer Henry F.⁵⁶⁷^ORCID

Affiliation:

1. School of Science

2. Research Center for Advanced Computation Xihua University

3. Chengdu 610039

4. China

5. Department of Chemistry and Center for Computational Chemistry University of Georgia

6. Athens

7. USA

Abstract

Density functional studies on (Me₄B₂N₂CH)₂M (M = Ti, V, Cr, Mn, Fe, Co, Ni) show low-energy sandwich structures for all seven metals. The lowest-energy such Cr and Mn derivatives have higher spin states than the corresponding metallocenes.

Funder

Division of Chemistry

Education Department of Sichuan Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/NJ/C8NJ05517C

Reference34 articles.

1. Electronic and structural properties of borazine and related molecules

2. Is Borazine Aromatic? Unusual Parallel Behavior between Hydrocarbons and Corresponding B−N Analogues

3. Tricarbonylhexamethylborazolechromium

4. Synthese und Eigenschaften von Hexaalkylborazolchromtricarbonylen

5. 1,2-Azaborolyls, Isoelectronic Analogues of the Ubiquitous Cyclopentadienyl Ligand: Synthesis of B-Heteroatom-Substituted 1,2-Azaborolyl Complexes and an Assessment of Their Electronic Features

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Cyclic and Non-Cyclic Pi Complexes of Manganese;Reference Module in Chemistry, Molecular Sciences and Chemical Engineering;2021