Mechanism and regioselectivity of the anionic oxidative rearrangement of 1,3-diketones towards all-carbon quaternary carboxylates-Reference-Cited by-同舟云学术

Mechanism and regioselectivity of the anionic oxidative rearrangement of 1,3-diketones towards all-carbon quaternary carboxylates

Published:2019 Issue:60 Volume:55 Page:8844-8847
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Bratt Emma¹²³⁴⁵,Suárez-Pantiga Samuel⁶⁷⁸⁹¹⁰^ORCID,Johansson Magnus J.¹²³⁴⁵,Mendoza Abraham⁶⁷⁸⁹¹⁰^ORCID

Affiliation:

1. Medicinal Chemistry

2. Research and Early Development Cardiovascular

3. Renal and Metabolism

4. BioPharmaceuticals R&D

5. AstraZeneca

6. Dept. of Organic Chemistry

7. Stockholm University

8. Arrhenius Laboratory

9. 106 91 Stockholm

10. Sweden

Abstract

The oxidative rearrangement of 1,3-diketones is an underexplored alternative to enolate chemistry in the synthesis of all-carbon quaternary carboxylates. Mechanistic understanding enabled the discovery of a faster and more effective reaction.

Funder

Knut och Alice Wallenbergs Stiftelse

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C9CC03331A

Reference33 articles.

1. Isolation of primary decomposition products of azides. II. Azidopyrazoles

2. Control of ring size resulting from .gamma.-epoxysulfone and .gamma.-epoxynitrile cyclization. Formation of either cyclopropyl or cyclobutyl derivatives

3. Potassium on alumina as a reagent for reductive decyanation of alkylnitriles

4. Expanding the Scope of C−H Amination through Catalyst Design

5. Über die α.α;α′.α′‐Bis‐[tetramethylen]‐adipinsäure. Ein Fall von Ringverengerung durch Oxydation

Cited by 10 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Asymmetric reactions involving aryne intermediates;Nature Reviews Chemistry;2023-03-31

2. Reactions of Aldehydes and Ketones and Their Derivatives;Organic Reaction Mechanisms Series;2023-01-20

3. Cooperative Rh(II)/Pd(0) Dual‐Catalyzed gem‐ Difunctionalization of α‐Diazo Carbonyl Compounds: Construction of Quaternary Carbon Centers;European Journal of Organic Chemistry;2022-07-09

4. Construction of CF3-Containing Quaternary Chiral Centers via Michael Addition Reactions;Bulletin of the Chemical Society of Japan;2021-07-15

5. Effective [3+1+1+1] Cycloaddition to Six‐Membered Carbocycle Based on DMSO as Dual Carbon Synthon;Advanced Synthesis & Catalysis;2021-05-06