Access to 5-fluoroalkylated trisubstituted oxazoles <i>via</i> copper-catalyzed cyclization of α-fluoroalkyl-α-diazoketones with amides-Reference-Cited by-同舟云学术

Access to 5-fluoroalkylated trisubstituted oxazoles via copper-catalyzed cyclization of α-fluoroalkyl-α-diazoketones with amides

Published:2022 Issue:31 Volume:58 Page:4853-4856
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Jiang Di¹,Jia Jingpei¹,Wang Baiquan¹²^ORCID,Li Bin¹^ORCID

Affiliation:

1. State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China

2. State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Abstract

We have developed a mechanistically distinct approach to furnish 5-fluoroalkylated trisubstituted oxazoles and thiazoles via copper-catalyzed cyclization of α-fluoroalkyl-α-diazoketones with (thio)amides.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Tianjin City

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC01057G

Reference63 articles.

1. J.Alvarez-Builla , J. J.Vaquero and J.Barluenga , Modern Heterocyclic Chemistry , Wiley-VCH , Weinheim , 1st edn, 2011

2. Fluorine in Medicinal Chemistry and Chemical Biology , ed. I. Ojima , Wiley-Blackwell , Chichester , 2009

3. Fluorine in medicinal chemistry

4. P.Kirsch , Modern Fluoroorganic Chemistry: Synthesis, Reactivity, and Applications , Wiley-VCH , Weinheim , 2004

5. Organofluorine Compounds: Chemistry and Applications , ed. T. Hiyama , Springer , New York , 2000

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