Modulating paired Ir–O–Ir <i>via</i> electronic perturbations of correlated Ir single atoms to overcome catalytic selectivity-Reference-Cited by-同舟云学术

Modulating paired Ir–O–Ir via electronic perturbations of correlated Ir single atoms to overcome catalytic selectivity

Published:2023 Issue:36 Volume:14 Page:9678-9688
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Chen Shi-Hua¹²,Yang Yuan-Fan¹³,Song Zong-Yin¹³,Xiao Xiang-Yu¹³,Huang Cong-Cong¹³,Cai Xin¹³,Li Pei-Hua¹,Yang Meng¹,Chen Aicheng⁴^ORCID,Liu Wen-Qing⁵,Huang Xing-Jiu¹²³^ORCID

Affiliation:

1. Key Laboratory of Environmental Optics and Technology, and Environmental Materials and Pollution Control Laboratory, Institute of Solid State Physics, HFIPS, Chinese Academy of Sciences, Hefei 230031, China

2. State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem And Information Technology, Chinese Academy of Sciences, Shanghai 200050, China

3. Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China

4. Department of Chemistry, University of Guelph, Guelph, ON N1G 2W1, Canada

5. Anhui Institute of Optics and Fine Mechanics, HFIPS, Chinese Academy of Sciences, Hefei 230031, China

Abstract

The active center of a paired Ir–O–Ir structure was generated via electronic perturbations of correlated Ir single atoms on Co3O4 nanosheets, and the O atom of which functioned as the main active site for the selective electrocatalysis of As(iii).

Funder

China Postdoctoral Science Foundation

National Natural Science Foundation of China

Natural Science Foundation of Anhui Province

Youth Innovation Promotion Association of the Chinese Academy of Sciences

National Key Research and Development Program of China

Chinese Academy of Sciences

Key Technologies Research and Development Program of Anhui Province

Fuyang Normal University

Publisher

Royal Society of Chemistry (RSC)

Subject