The effect of pore diameter in the arrangement of chelating species grafted onto silica surfaces with application to uranium extraction
Author:
Affiliation:
1. CEA
2. DEN
3. DTCD
4. SPDE
5. Laboratoire des Procédés Supercritiques et de Décontamination
6. DRCP
7. SMCS
8. Laboratoire de Développement des Procédés de Séparation
Abstract
A series of five silica supports were functionalized producing three types of material: (1) supports with pores smaller than 4 nm are heterogeneously functionalized (2) when the pores range from 5 to 20 nm in diameter, a homogeneous organic monolayer is grafted (3) when the pores are larger than 30 nm, an organic multilayer is obtained.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2017/NJ/C6NJ03017C
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4. Polymer-Supported Aminomethylphosphinate as a Ligand with a High Affinity for U(VI) from Phosphoric Acid Solutions: Combining Variables to Optimize Ligand–Ion Communication
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