Nanocrystals of Fe(phen)2(NCS)2 and the size-dependent spin-crossover characteristics

Author:

Laisney J.12345,Tissot A.12345,Molnár G.6789,Rechignat L.6789,Rivière E.12345,Brisset F.12345,Bousseksou A.6789,Boillot M.-L.12345

Affiliation:

1. ICMMO-ECI

2. UMR CNRS 8182

3. Univ. Paris-Sud

4. Université Paris-Saclay

5. 91405 Orsay

6. LCC

7. UPR CNRS 8241

8. 31077 Toulouse cedex 04

9. France

Abstract

We describe the preparation of nano- and microcrystals of the Fe(phen)2(NCS)2 spin-crossover prototypical compound based on the solvent-assisted technique applied to an ionic and soluble precursor and analyze the size-dependent characteristics of the thermal spin-crossover.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference51 articles.

1. P. Gütlich and H. A.Goodwin, Spin-Crossover in Transition Metal Compounds, I–III, in Topics in Current Chemistry, Springer, Berlin, 2004, vol. 233–235; Special issue in: Eur. J. Inorg. Chem., 2013, 5–6

2. Spin-crossover materials: Properties and Applications, ed. M. A. Halcrow, Wiley, Chichester, UK, 2013

3. Thermo-, piezo-, photo- and chemo-switchable spin crossover iron(II)-metallocyanate based coordination polymers

4. C. Boskovic , in Spin-crossover materials: Properties and Applications, ed. M. A. Halcrow, Wiley, Chichester, UK, 2013, pp. 203–224

5. K. R. Dunbar , C.Achim and M.Shatruk, in Spin-Crossover Materials: Properties and Applications, ed. M. A. Halcrow, John Wiley & Sons, Ltd, 1st edn, 2013, pp. 171–202

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