Mild partial deoxygenation of esters catalyzed by an oxazolinylborate-coordinated rhodium silylene-Reference-Cited by-同舟云学术

Mild partial deoxygenation of esters catalyzed by an oxazolinylborate-coordinated rhodium silylene

Published:2015 Issue:36 Volume:44 Page:15897-15904
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Xu Songchen¹²³⁴,Boschen Jeffery S.¹²³⁴,Biswas Abhranil¹²³⁴,Kobayashi Takeshi¹²³⁴,Pruski Marek¹²³⁴,Windus Theresa L.¹²³⁴,Sadow Aaron D.¹²³⁴

Affiliation:

1. U.S. Department of Energy Ames Laboratory and Department of Chemistry

2. Iowa State University

3. Ames

4. USA

Abstract

An oxazoline-stabilized rhodium silylene complex catalyzes the deoxygenation of carbonyls using PhSiH₃as the reductant, including esters to ethers, amides to amines, and ketones to hydrocarbons rapidly at room temperature.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02844B

Reference63 articles.

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4. An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol. Mechanistic studies of a formic acid-mediated deoxygenation

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