A new nitrogen fixation strategy: the direct formation of *N2− excited state on metal-free photocatalyst-Reference-Cited by-同舟云学术

A new nitrogen fixation strategy: the direct formation of *N2− excited state on metal-free photocatalyst

Published:2021 Issue:10 Volume:9 Page:6214-6222
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Niu Xianghong¹²³⁴⁵^ORCID,Sun Dazhong¹²³⁴⁵,Shi Li⁶⁷⁸⁵,Bai Xiaowan⁶⁷⁸⁵,Li Qiang⁶⁷⁸⁵^ORCID,Li Xing'ao¹²³⁴⁵^ORCID,Wang Jinlan⁶⁷⁸⁵^ORCID

Affiliation:

1. New Energy Technology Engineering Laboratory of Jiangsu Province

2. School of Science

3. Nanjing University of Posts and Telecommunications

4. Nanjing 210023

5. China

6. School of Physics

7. Southeast University

8. Nanjing 211189

Abstract

For photocatalytic N₂ fixation, electrons at the valence-band edge of the photocatalyst can be directly excited to π* orbitals, which not only significantly activates N₂, but also effectively improves the selectivity.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/TA/D1TA00298H

Reference71 articles.

1. Nitrogen fixation and reduction at boron

2. How to explore ambient electrocatalytic nitrogen reduction reliably and insightfully

3. Greening Ammonia toward the Solar Ammonia Refinery

4. Anion (O, N, C, and S) vacancies promoted photocatalytic nitrogen fixation

5. Promoting nitrogen electroreduction to ammonia with bismuth nanocrystals and potassium cations in water

Cited by 10 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Unraveling the Photocatalytic Mechanism of N₂ Fixation on Single Ruthenium Sites;The Journal of Physical Chemistry Letters;2024-07-23

2. Gold-diamond Nanocomposites Efficiently Generate Hydrated Electrons upon Absorption of Visible Light;ACS Applied Optical Materials;2024-06-17

3. Ru@MOF@H-C3N4 heterojunction for visibleṇ light photocatalytic nitrogen fixation;Journal of Photochemistry and Photobiology A: Chemistry;2024-01

4. The regulating effect of boron doping and its concentration on the photocatalytic overall water splitting of a polarized g-C₃N₅ material;Physical Chemistry Chemical Physics;2023

5. Double Heterojunction Ru@Mof@H-C3n4 for Visible Light Photocatalytic Nitrogen Fixation;2023