Magnesium cations as templates for the self-assembly of supramolecular luminescent {Mg@[B18φ34–35]}-clusters

Author:

Volkov Sergey12ORCID,Yukhno Valentina2,Banaru Alexander31ORCID,Deyneko Dina31ORCID,Aksenov Sergey14ORCID,Charkin Dmitri31,Povolotskiy Alexey5,Savchenko Yevgeny46ORCID,Antonov Andrey7,Krzhizhanovskaya Maria82,Ugolkov Valery2,Firsova Vera2,Vaitieva Yulia1,Boldyrev Kirill9ORCID,Bubnova Rimma2

Affiliation:

1. Laboratory of Arctic Mineralogy and Material Sciences, Kola Science Centre, Russian Academy of Sciences, Apatity, Russia

2. Grebenshchikov Institute of Silicate Chemistry, St Petersburg, Russia

3. Department of Chemistry, Lomonosov Moscow State University, Moscow, Russia

4. Geological Institute, Kola Science Centre, Russian Academy of Sciences, Apatity, Russia

5. Institute of Chemistry, Saint Petersburg State University, St Petersburg, Russia

6. Nanomaterials Research Centre, Kola Science Centre, Russian Academy of Sciences, Apatity, Russia

7. Laboratory of Nature-Inspired Technologies and Environmental Safety of the Arctic, Kola Science Centre, Russian Academy of Sciences, Apatity, Russia

8. Department of Crystallography, Saint Petersburg State University, St Petersburg, Russia

9. Institute of Spectroscopy of the Russian Academy of Sciences, Fizicheskaya Str. 5, Troitsk, Moscow, 108840, Russia

Abstract

Solvothermal reaction of magnesium nitrate and boron oxide in N,N-dimethylformamide produced a number of particularly complex supramolecular magnesium borates.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

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