Synthesis and reactivity of phosphine borohydride compounds-Reference-Cited by-同舟云学术

Synthesis and reactivity of phosphine borohydride compounds

Published:2021 Issue:3 Volume:57 Page:375-378
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ayyappan Ramaraj¹²³⁴⁵^ORCID,Coppel Yannick¹²³⁴⁵^ORCID,Vendier Laure¹²³⁴⁵,Ghosh Sundargopal⁶⁷⁸⁹^ORCID,Sabo-Etienne Sylviane¹²³⁴⁵^ORCID,Bontemps Sébastien¹²³⁴⁵^ORCID

Affiliation:

1. LCC-CNRS

2. Université de Toulouse

3. CNRS

4. 31077 Toulouse Cedex 04

5. France

6. Department of Chemistry

7. Indian Institute of Technology Madras

8. Chennai 600036

9. India

Abstract

Strong evidence for non-bonded through space P–B coupling are obtained by close positioning of phosphine and borate moieties. The new species readily release LiH to carbonyl and generate phosphine borane ambiphilic compounds.

Funder

Centre National de la Recherche Scientifique

Indo-French Centre for the Promotion of Advanced Research

Université de Toulouse

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D0CC07072F

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3. Forty years of hydride reductions

4. Reduction of CO2 to Trimethoxyboroxine with BH3 in THF

5. Alkali Metal Hydridotriphenylborates [(L)M][HBPh3] (M = Li, Na, K): Chemoselective Catalysts for Carbonyl and CO2 Hydroboration

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