Conformationally dynamic titanium and zirconium cationic complexes of bis(naphthoxy)pyridine ligands: structure, “oscillation” and olefin polymerization catalysis

Author:

Annunziata Liana12345,Roisnel Thierry12345,Razavi Abbas678,Carpentier Jean-François12345,Kirillov Evgueni12345ORCID

Affiliation:

1. Université de Rennes 1

2. CNRS

3. Institut des Sciences Chimiques de Rennes

4. F-35042 Rennes Cedex

5. France

6. Total Petrochemicals Research

7. B-7181 Feluy

8. Belgium

Abstract

The interconversion and reorganization processes occurring in cationic Ti and Zr complexes were studied by NMR techniques and DFT computations.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference58 articles.

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2. G. Fink and H. H.Brintzinger, Metal-Catalysis in Industrial Organic Processes ed. G. P. Chiusoli and P. M. Maitlis, Royal Society of Chemistry, Colchester, 2006, pp. 218–254

3. Oscillating Stereocontrol: A Strategy for the Synthesis of Thermoplastic Elastomeric Polypropylene

4. Oscillating Catalysts: A New Twist for Plastics

5. Stereoblock Polypropylene: Ligand Effects on the Stereospecificity of 2-Arylindene Zirconocene Catalysts

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