Sulfur dots–graphene nanohybrid: a metal-free electrocatalyst for efficient N2-to-NH3 fixation under ambient conditions

Author:

Chen Hongyu12345ORCID,Zhu Xiaojuan12345,Huang Hong6785ORCID,Wang Huanbo910115,Wang Ting12345ORCID,Zhao Runbo6785ORCID,Zheng Hongguo12135,Asiri Abdullah M.1415161718ORCID,Luo Yonglan12345ORCID,Sun Xuping12345ORCID

Affiliation:

1. Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province

2. School of Chemistry and Chemical Engineering

3. China West Normal University

4. Nanchong 637002

5. China

6. Institute of Fundamental and Frontier Sciences

7. University of Electronic Science and Technology of China

8. Chengdu

9. School of Environment and Resource

10. Southwest University of Science and Technology

11. Mianyang 621010

12. ThermoFisher Scientific

13. Chengdu 610023

14. Chemistry Department

15. Faculty of Science & Center of Excellence for Advanced Materials Research

16. King Abdulaziz University

17. Jeddah 21589

18. Saudi Arabia

Abstract

Sulfur dots–graphene nanohybrids act as an efficient electrocatalyst for the conversion of N2 to NH3 in 0.5 M LiClO4, achieving a high NH3 yield of 28.56 μg h−1 mgcat.−1 and a Faradaic efficiency of 7.07% at −0.85 V vs. RHE.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference46 articles.

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5. J. R. Jennings , Catalytic ammonia synthesis: fundamentals and practice , Spring Science & Business Media , 1991

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