Ultrafast SET-LRP of hydrophobic acrylates in multiphase alcohol–water mixtures-Reference-Cited by-同舟云学术

Ultrafast SET-LRP of hydrophobic acrylates in multiphase alcohol–water mixtures

Published:2016 Issue:21 Volume:7 Page:3608-3621
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Enayati Mojtaba¹²³⁴⁵,Jezorek Ryan L.¹²³⁴⁵,Monteiro Michael J.⁶⁷⁸⁹,Percec Virgil¹²³⁴⁵

Affiliation:

1. Roy & Diana Vagelos Laboratories

2. Department of Chemistry

3. University of Pennsylvania

4. Philadelphia

5. USA

6. Australian Institute for Bioengineering and Nanotechnology

7. The University of Queensland

8. Brisbane QLD 4072

9. Australia

Abstract

A multiphase SET-LRP system using thein situgenerated Cu(0) by reduction of Cu(ii)Br₂with NaBH₄in various alcohols containing water was developed and used for SET-LRP of hydrophobic acrylates. From left to right: a solution of methanol/water containing Cu(ii)Br₂, the same solution after addition of BA and its SET-LRP.

Funder

Division of Materials Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2016/PY/C6PY00353B

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3. Ultrafast Synthesis of Ultrahigh Molar Mass Polymers by Metal-Catalyzed Living Radical Polymerization of Acrylates, Methacrylates, and Vinyl Chloride Mediated by SET at 25 °C