Unprecedented observation and characterization of sulfur-centred bifurcated hydrogen bonds

Author:

Ma Xiantao1ORCID,Zhu Yingying1,Yu Jing1,Zhao Geng1,Duanmu Jiaxin1,Yuan Yiyun1,Chang Xue-Ping1,Xu Dongli1,Zhou Qiuju1

Affiliation:

1. College of Chemistry and Chemical Engineering, Green Catalysis & Synthesis Key Laboratory of Xinyang City, Xinyang Normal University, Xinyang, Henan 464000, China

Abstract

It is observed that the sulfur atom can unprecedentedly serve as a good acceptor to form the O–H⋯S⋯H–O bifurcated H-bond.

Funder

National Natural Science Foundation of China

Key Scientific Research Project of Colleges and Universities in Henan Province

Nanhu Scholars Program for Young Scholars of Xinyang Normal University

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference42 articles.

1. The centenary (maybe) of the hydrogen bond

2. Quantum nature of the hydrogen bond

3. Noncovalent Interactions in C–S Bond Formation Reactions

4. T.Marcelli , in Double Hydrogen Bonding in Asymmetric Organocatalysis: A Mechanistic Perspective in Ideas in Chemistry and Molecular Science: Advances in Synthetic Chemistry , ed. B. Pignataro , Wiley-VCH , Weinheim , 2010 , Chapter 6, pp. 115–141

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