Hydrogen activation with perfluorinated organoboranes: 1,2,3-tris(pentafluorophenyl)-4,5,6,7-tetrafluoro-1-boraindene-Reference-Cited by-同舟云学术

Hydrogen activation with perfluorinated organoboranes: 1,2,3-tris(pentafluorophenyl)-4,5,6,7-tetrafluoro-1-boraindene

Published:2014 Issue:11 Volume:50 Page:1295-1298
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Houghton Adrian Y.¹²³,Karttunen Virve A.¹⁴⁵,Piers Warren E.¹²³,Tuononen Heikki M.¹⁴⁵

Affiliation:

1. Department of Chemistry

2. University of Calgary

3. Calgary, Canada T2N 1N4

4. University of Jyväskylä

5. Jyväskylä, Finland

Abstract

Experimental and computational data shows that a new perfluorinated boraindene reacts reversibly with H₂ to form a reactive hydroborane that can be trapped with an olefin.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C3CC48796B

Reference25 articles.

1. W. E. Piers , Adv. Organomet. Chem. , Academic Press , 2004 , vol. 52, pp. 1–76

2. Pentafluorophenylboranes: from obscurity to applications

3. Tris(pentafluorophenyl)borane: a special boron Lewis acid for special reactions

4. Cocatalysts for Metal-Catalyzed Olefin Polymerization: Activators, Activation Processes, and Structure−Activity Relationships

5. Arylboron Compounds as Acid Catalysts in Organic Synthetic Transformations

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