Insertion of terminal alkyne into Pt–N bond of the square planar [PtI2(Me2phen)] complex-Reference-Cited by-同舟云学术

Insertion of terminal alkyne into Pt–N bond of the square planar [PtI2(Me2phen)] complex

Published:2017 Issue:45 Volume:46 Page:15819-15826
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Benedetti Michele¹²³⁴^ORCID,De Castro Federica¹²³⁴^ORCID,Lamacchia Vincenza⁵⁶⁷⁴,Pacifico Concetta⁵⁶⁷⁴,Natile Giovanni⁵⁶⁷⁴,Fanizzi Francesco P.¹²³⁴^ORCID

Affiliation:

1. Dipartimento di Scienze e Tecnologie Biologiche ed Ambientali

2. Università del Salento

3. I-73100 Lecce

4. Italy

5. Dipartimento di Chimica

6. Università degli Studi di Bari

7. I-70125 Bari

Abstract

The reactivity of [PtX₂(Me₂phen)] complexes (X = Cl, Br, I; Me₂phen = 2,9-dimethyl-1,10-phenanthroline) with terminal alkynes is reported. Bromo and iodo derivatives lead to the formation of Pt(ii) alkenyl derivatives of the type [PtX₂{κ²-N,C-(Z)-N̲1–N10–C̲C(H)(R)}] (N1–N10 = Me₂phen) containing a Pt–N–C–C–N–C six membered metallacycle.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT03644B

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