Pre-phase transition of a Cu2−xS template enables polymorph selective synthesis of MS (M = Zn, Cd, Mn) nanocrystals via cation exchange reactions

Author:

Zhang Yan12,He Shaobo1,Zhang Qingxia1,Zhang Hongtao1,Zhou Jinchen1,Yang Xing1,Wei Qinhong1ORCID,Chen Lihui134ORCID

Affiliation:

1. School of Petrochemical Engineering & Environment, Zhejiang Ocean University, No.1, Haida South Road, Lincheng Changzhi Island, Zhoushan 316022, China

2. School of Naval Architecture and Maritime, Zhejiang Ocean University, No.1, Haida South Road, Lincheng Changzhi Island, Zhoushan 316022, China

3. Zhejiang Key Laboratory of Petrochemical Environmental Pollution Control, Zhoushan 316022, China

4. National & Local Joint Engineering Research Center of Harbor Oil & Gas Storage and Transportation Technology, Zhoushan 316022, China

Abstract

A pre-phase transition of covellite CuS into hcp Cu1.94S and ccp Cu1.8S by two reducing agents was reported and subsequent polymorphic synthesis of wurtzite and zinc blende MS (M = Zn, Cd, Mn) nanocrystals via a cation exchange reaction was developed.

Funder

Natural Science Foundation of Zhejiang Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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