Reaction of tin(iv) phthalocyanine dichloride with decamethylmetallocenes (M = CrII and CoII). Strong magnetic coupling of spins in (Cp*2Co+){SnIVCl2(Pc˙3−)}˙−·2C6H4Cl2-Reference-Cited by-同舟云学术

Reaction of tin(iv) phthalocyanine dichloride with decamethylmetallocenes (M = CrII and CoII). Strong magnetic coupling of spins in (Cp*2Co+){SnIVCl2(Pc˙3−)}˙−·2C6H4Cl2

Published:2018 Issue:4 Volume:47 Page:1243-1250
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Konarev Dmitri V.¹²³^ORCID,Troyanov Sergey I.⁴⁵⁶⁷^ORCID,Shestakov Alexander F.¹²³,Yudanova Evgeniya I.¹²³,Otsuka Akihiro⁸⁹¹⁰¹¹¹²,Yamochi Hideki⁸⁹¹⁰¹¹¹²,Kitagawa Hiroshi⁸⁹¹⁰¹¹¹²^ORCID,Lyubovskaya Rimma N.¹²³

Affiliation:

1. Institute of Problems of Chemical Physics RAS

2. Chernogolovka

3. 142432 Russia

4. Chemistry Department

5. Moscow State University

6. 119991 Moscow

7. Russia

8. Division of Chemistry

9. Graduate School of Science

10. Kyoto University

11. Kyoto 606-8502

12. Japan

Abstract

Decamethylmetallocenes form complexes (Cp*₂Co⁺){Sn^IVCl₂(Pc˙³⁻)}˙⁻·2C₆H₄Cl₂ (1) and {(Cp*CrCl₂)(Sn^IVCl(Pc²⁻))}·C₆H₄Cl₂ (2) whose structures and properties are discussed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT03807K

Reference35 articles.

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4. A highly conducting partially oxidized salt of axially substituted phthalocyanine. Structure and physical properties of TPP[Co(Pc)(CN)2]2 {TPP=tetraphenylphosphonium, [Co(Pc)(CN)2]=dicyano(phthalocyaninato)cobalt(III)}

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