Pyridine-<i>N</i>-oxide catalyzed acylative desymmetrization of bisphenols: access to P-stereogenic phosphinates with low catalyst loadings-Reference-Cited by-同舟云学术

Pyridine-N-oxide catalyzed acylative desymmetrization of bisphenols: access to P-stereogenic phosphinates with low catalyst loadings

Published:2023 Issue:24 Volume:10 Page:6140-6145
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Chen Yang-Guang¹,Hu Ying²,Liu Jia-Yi²,Xie Ming-Sheng²^ORCID,Guo Hai-Ming¹²^ORCID

Affiliation:

1. School of Environment, Henan Normal University, Xinxiang, Henan 453007, China

2. State Key Laboratory of Antiviral Drugs, Pingyuan Laboratory, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, China

Abstract

A catalytic stereoselective strategy to access P-stereogenic phosphinates through chiral 4-arylpyridine-N-oxide-catalyzed acylative desymmetrization of bisphenols has been reported.

Funder

Henan Key Laboratory of Organic Functional Molecules and Drug Innovation

Science and Technology Innovation Talents in Universities of Henan Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D3QO01499A

Reference48 articles.

1. New Chiral Phosphorus Ligands for Enantioselective Hydrogenation

2. Applications and stereoselective syntheses of P-chirogenic phosphorus compounds

3. Phosphine−Phosphinite and Phosphine−Phosphite Ligands: Preparation and Applications in Asymmetric Catalysis

4. Development of Ruthenium Catalysts for the Enantioselective Synthesis of P-Stereogenic Phosphines via Nucleophilic Phosphido Intermediates