Nickel-catalyzed regio- and diastereoselective hydroarylative and hydroalkenylative cyclization of 1,6-dienes-Reference-Cited by-同舟云学术

Nickel-catalyzed regio- and diastereoselective hydroarylative and hydroalkenylative cyclization of 1,6-dienes

Published:2020 Issue:56 Volume:56 Page:7741-7744
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Xu Zhengshuai¹²³⁴⁵,Tang Yitian¹²³⁴⁵,Shen Chaoren¹²³⁴⁵^ORCID,Zhang Hongru¹²³⁴⁵,Gan Yuxin¹²³⁴⁵^ORCID,Ji Xiaolei¹²³⁴⁵,Tian Xinxin⁶⁷⁸⁹¹⁰^ORCID,Dong Kaiwu¹²³⁴⁵^ORCID

Affiliation:

1. Chang-Kung Chuang Institute

2. Shanghai Key Laboratory of Green Chemistry and Chemical Process

3. School of Chemistry and Molecular Engineering

4. East China Normal University

5. Shanghai 200241

6. Institute of Molecular Science

7. Key Laboratory of Materials for Energy Conversion and Storage of Shanxi Province

8. Shanxi University

9. Taiyuan 030006

10. China

Abstract

By using methanol as the hydrogen source and commercially available nickel complex as the catalyst, the hydroarylative and hydroalkenylative cyclization of unsymmetrically substituted 1,6-dienes with organoboronic acid was developed to afford products with high regio- and diastereoselectivities.

Funder

National Natural Science Foundation of China

East China Normal University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/C9CC09450D

Reference59 articles.

1. Gold-Catalyzed Cycloisomerizations of Enynes: A Mechanistic Perspective

2. Cyclic Carbopalladation. A Versatile Synthetic Methodology for the Construction of Cyclic Organic Compounds

3. Transition Metal-Catalyzed Carbocyclizations in Organic Synthesis

4. The Behavior of 1,n-Enynes in the Presence of Transition Metals

5. Nickel-Catalyzed Reductive Cyclizations and Couplings

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