Structure and dynamics of heterometallic clusters derived from addition of metal carbonyl fragments to the unsaturated hydride [W2Cp2(μ-H)(μ-PPh2)(NO)2]

Author:

Angeles Alvarez M.1234,Esther García M.1234ORCID,García-Vivó Daniel1234ORCID,Ruiz Miguel A.1234ORCID,Toyos Adrián1234

Affiliation:

1. Departamento de Química Orgánica e Inorgánica/IUQOEM

2. Universidad de Oviedo

3. E-33071 Oviedo

4. Spain

Abstract

Metal carbonyl fragments may insert or add to the title complex, and even replace the hydride ligand to give heterometallic clusters.

Funder

Secretaría de Estado de Investigación, Desarrollo e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference83 articles.

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2. R. D. Adams and F. A.Cotton , Catalysis by Di- and Polynuclear Metal Complexes , Wiley-VCH , New York, USA , 1998

3. P. Braunstein , L. A.Oro and P. R.Raithby , Metal Clusters in Chemistry , Wiley-VCH , Weinheim, Germany , 1999 , vol. 1 and 2

4. Metal Carbonyl-Gold Nanoparticle Conjugates for Live-Cell SERS Imaging

5. Carbonylate anion [(μ-H)Os3(CO)10L]− as a precursor in the synthesis of heterometallic Os3M clusters

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