A computational study of the reactivity of rare-earth/phosphorus Lewis pairs toward polymerization of conjugated polar alkenes-Reference-Cited by-同舟云学术

A computational study of the reactivity of rare-earth/phosphorus Lewis pairs toward polymerization of conjugated polar alkenes

Published:2020 Issue:23 Volume:7 Page:4600-4610
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Zhao Yanan¹²³⁴⁵^ORCID,Luo Gen¹²³⁴⁵^ORCID,Xu Xin⁶⁷⁸⁹¹⁰^ORCID,Hou Zhaomin¹²³⁴⁵^ORCID,Luo Yi¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Fine Chemicals

2. School of Chemical Engineering

3. Dalian University of Technology

4. Dalian 116024

5. China

6. Key Laboratory of Organic Synthesis of Jiangsu Province

7. College of Chemistry

8. Chemical Engineering and Materials Science

9. Soochow University

10. Suzhou 215123

Abstract

The polymerization mechanism of methyl methacrylate (MMA) catalyzed by rare-earth/phosphorus (RE/P) Lewis pairs has been systematically studied through density functional theory (DFT) calculations.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/QI/D0QI01067G

Reference60 articles.

1. Regiospecific Radical Polymerization of Vinyl Methacrylate in the Presence of Lewis Acids into Soluble Polymers with Pendent Vinyl Ester Substituents

2. Well-Defined Polymers Bearing Pendent Alkene Functionalities via Selective RAFT Polymerization

3. Reactive Polymers Bearing Styrene Pendants through Selective Anionic Polymerization of 4-Vinylbenzyl Methacrylate

4. Synthesis of Well-Defined Novel Reactive Block Polymers Containing a Poly(1,4-divinylbenzene) Segment by Living Anionic Polymerization

5. Designing catalysts for olefin polymerization and copolymerization: beyond electronic and steric tuning

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