Synthesis of mixed-valence hexanuclear Mn(ii/iii) clusters from its Mn(ii) precursor: variations of catecholase-like activity and magnetic coupling-Reference-Cited by-同舟云学术

Synthesis of mixed-valence hexanuclear Mn(ii/iii) clusters from its Mn(ii) precursor: variations of catecholase-like activity and magnetic coupling

Published:2015 Issue:21 Volume:44 Page:9795-9804
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kar Paramita¹²³⁴⁵,Ida Yumi⁶⁷⁸⁹,Kanetomo Takuya⁶⁷⁸⁹,Drew Michael G. B.¹⁰¹¹¹²¹³,Ishida Takayuki⁶⁷⁸⁹,Ghosh Ashutosh¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. University College of Science

3. University of Calcutta

4. Kolkata-700 009

5. India

6. Department of Engineering Science

7. The University of Electro-Communications

8. Tokyo 182-8585

9. Japan

10. School of Chemistry

11. The University of Reading

12. Reading RG6 6AD

13. UK

Abstract

A pyrazine bridged 1D coordination polymer of Mn(ii) has been oxidized with n-Bu₄NMnO₄ to hexanuclear Mn(ii/iii) complexes. Their catecholase-like activities and magnetic interactions have been studied.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00709G

Reference74 articles.

1. Theoretical Methods Enlighten Magnetic Properties of a Family of Mn6 Single-Molecule Magnets

2. Validity of the Classical Monte Carlo Method To Model the Magnetic Properties of a Large Transition-Metal Cluster: Mn19

3. A Reductive-Aggregation Route to [Mn12O12(OMe)2(O2CPh)16(H2O)2]2? Single-Molecule Magnets Related to the [Mn12] Family

4. Rare Oxidation-State Combinations and Unusual Structural Motifs in Hexanuclear Mn Complexes Using 2-Pyridyloximate Ligands

5. Supramolecular Entanglement from Interlocked Molecular Nanomagnets

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