Synchrotron-based X-ray spectromicroscopy and electron paramagnetic resonance spectroscopy to investigate the redox properties of lead chromate pigments under the effect of visible light-Reference-Cited by-同舟云学术

Synchrotron-based X-ray spectromicroscopy and electron paramagnetic resonance spectroscopy to investigate the redox properties of lead chromate pigments under the effect of visible light

Published:2015 Issue:7 Volume:30 Page:1500-1510
ISSN:0267-9477
Container-title:Journal of Analytical Atomic Spectrometry
language:en
Short-container-title:J. Anal. At. Spectrom.

Author:

Monico Letizia¹²³⁴⁵,Janssens Koen⁶⁷⁸⁹,Cotte Marine¹⁰¹¹¹²¹³¹⁴,Romani Aldo¹²³⁴⁵,Sorace Lorenzo¹⁵¹⁶¹⁷¹⁸,Grazia Chiara¹²³⁴⁵,Brunetti Brunetto Giovanni¹²³⁴⁵,Miliani Costanza¹²³⁴⁵

Affiliation:

1. CNR Institute of Molecular Science and Technologies (CNR-ISTM) and Centre SMAArt

2. c/o Department of Chemistry

3. Biology and Biotechnologies

4. University of Perugia

5. 06123 Perugia

6. Department of Chemistry

7. University of Antwerp

8. 2020 Antwerp

9. Belgium

10. European Synchrotron Radiation Facility

11. 38000 Grenoble

12. France

13. Laboratoire d'Archéologie Moléculaire et Structurale (LAMS)

14. CNRS-UPMC

15. Department of Chemistry “U. Schiff” and INSTM RU

16. University of Florence

17. 50019 Sesto Fiorentino

18. Italy

Abstract

The redox properties of chrome yellows under visible and monochromatic light exposure are studied using UV-vis, SR μ-XRF/μ-XANES and EPR spectroscopies.

Publisher

Royal Society of Chemistry (RSC)

Subject

Spectroscopy,Analytical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/JA/C5JA00091B

Reference46 articles.

1. The use of microscopic X-ray diffraction for the study of HgS and its degradation products corderoite (α-Hg3S2Cl2), kenhsuite (γ-Hg3S2Cl2) and calomel (Hg2Cl2) in historical paintings

2. Thermodynamic and experimental study of the degradation of the red pigment mercury sulfide

3. Tracking the transformation and transport of arsenic sulfide pigments in paints: synchrotron-based X-ray micro-analyses

4. Characterization of a Degraded Cadmium Yellow (CdS) Pigment in an Oil Painting by Means of Synchrotron Radiation Based X-ray Techniques

5. Combined use of Synchrotron Radiation Based Micro-X-ray Fluorescence, Micro-X-ray Diffraction, Micro-X-ray Absorption Near-Edge, and Micro-Fourier Transform Infrared Spectroscopies for Revealing an Alternative Degradation Pathway of the Pigment Cadmium Yellow in a Painting by Van Gogh

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