First observation of electrode-correlated protonic conductivity of perovskite-type electrolytes and way towards optimization

Author:

Luo Zhixin1ORCID,Tang Jiayi1,Wang Zehua1,Yang Guangming2ORCID,Zhu Tianjiu13,Lin Zezhou14ORCID,Jiang San Ping15ORCID,Shao Zongping1ORCID

Affiliation:

1. WA School of Mines: Minerals, Energy & Chemical Engineering (WASM-MECE), Curtin University, Perth, WA 6102, Australia

2. State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China

3. School of Chemical Engineering, The University of Queensland, QLD 4072, Australia

4. Department of Applied Physics and Research Institute for Smart Energy, The Hong Kong Polytechnic University, Hong Kong 999077, China

5. Foshan Xianhu Laboratory of the Advanced Energy Science and Technology Guangdong Laboratory, Foshan 528216, China

Abstract

Comparing symmetric cells with oxygen-ion and protonic conductive electrolytes, using distinct electrodes, shows that electrode hydration strongly affects proton-conductivity in defective perovskite electrolytes.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

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