Asymmetric total synthesis of (+)-dihydroitomanallene B and formal synthesis of (−)-kumausallene-Reference-Cited by-同舟云学术

Asymmetric total synthesis of (+)-dihydroitomanallene B and formal synthesis of (−)-kumausallene

Published:2022 Issue:85 Volume:58 Page:11921-11924
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Fernandes Rodney A.¹^ORCID,Kumar Atul¹^ORCID,Pathare Ramdas S.¹

Affiliation:

1. Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai 400 076, India

Abstract

The first total synthesis of (+)-dihydroitomanallene B and its two diastereomers, and the formal synthesis of (−)-kumausallene from a common intermediate based on protecting-group-directed Tsuji–Trost cyclization of allyl acetates are reported.

Funder

Science and Engineering Research Board

Indian Institute of Technology Bombay

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC04574E

Reference23 articles.

1. Allenic and cumulenic lipids

2. Halogenated Organic Molecules of Rhodomelaceae Origin: Chemistry and Biology

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4. A New Bromoallene-Producing Chemical Type of the Red Alga Laurencia nangii Masuda

5. KUMAUSYNES AND DEACETYLKUMAUSYNES, FOUR NEW HALOGENATED C-15 ACETYLENES FROM THE RED ALGALAURENCIA NIPPONICAYAMADA

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