Influence of the Lewis basicity hardness of crystallization solvents on the coordination sphere of the complex [Co(3,5-dinitrobenzoate-O,O′)2]: crystallographic and theoretical analysis

Author:

Fonseca Daniela1,Pérez-Torres Andrés F.2,Cobo Justo3,Zapata-Rivera Jhon4ORCID,Hurtado John J.1ORCID,Macías Mario A.2ORCID

Affiliation:

1. Inorganic Chemistry, Catalysis and Bio-inorganic Group, Department of Chemistry, Universidad de los Andes, Carrera 1 No. 18A-12, 111711 Bogotá, Colombia

2. Crystallography and Chemistry of Materials, CrisQuimMat, Department of Chemistry, Universidad de los Andes, Carrera 1 No. 18A-10, 111711 Bogotá, Colombia

3. Departamento de Química Inorgánica y Orgánica Campus las Lagunillas, Universidad de Jaén, E-23071 Jaén, Spain

4. Molecular Electronic Structure Group, Department of Chemistry, Universidad de los Andes, Carrera 1 No. 18A-10, 111711 Bogotá, Colombia

Abstract

Crystal growth of [Co(DNB)2] in different solvents is a thermodynamic process favored by ΔErecrys (kcal mol−1) where mono/trinuclear molecules are obtained. Closeness of HOMO orbitals of solvents to the SOMOs orbitals of Co(ii) ions guide the process.

Funder

Universidad de Jaén

Universidad de los Andes

Junta de Andalucía

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3