The mechanistic investigations of photochemical decarbonylations and oxidative addition reactions for M(CO)5 (M = Fe, Ru, Os) complexes

Author:

Zhang Zheng-Feng1234,Su Ming-Der12345ORCID

Affiliation:

1. Department of Applied Chemistry

2. National Chiayi University

3. Chiayi 60004

4. Taiwan

5. Department of Medicinal and Applied Chemistry

Abstract

Model study of the photoactivation reactions for Si–H bonds in trimethylsilane for group 8 M(CO)5 (M = Fe, Ru, and Os) complexes using the CASSCF and MP2-CAS levels of theory.

Funder

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Reference89 articles.

1. Photochemistry of metal carbonyls

2. Enlightening organometallic chemistry: the photochemistry of Fe(CO)5 and the reaction chemistry of unsaturated iron carbonyl fragments

3. F. W.Grevels , in Photoprocesses in Transition Metal Complexes, Biosystems and Other Molecules , ed. E. Kochanski , Kluwer , Amsterdam , 1992

4. G. L.Geoffroy and M. S.Wrighton , in Organometallic Photochemistry , Academic Press , New York , 1979

5. V.Balzani and V.Carassiti , in Photochemistry of Coordination Compounds , Academic Press , London , 1970

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