Effects of sodium cationization versus protonation on the conformations and N-glycosidic bond stabilities of sodium cationized Urd and dUrd: solution conformation of [Urd+Na]+ is preserved upon ESI
Author:
Affiliation:
1. Department of Chemistry
2. Wayne State University
3. Detroit
4. USA
5. Radboud University
6. Institute for Molecules and Materials
7. FELIX Laboratory
8. 6525ED Nijmegen
9. The Netherlands
Abstract
The conformations of sodium cationized uridine and 2′-deoxyuridine are sensitive to the presence (or absence) of the 2′-hydroxyl substituent. IRMPD action spectroscopy studies suggest that the solution conformation of [Urd+Na]+ is preserved upon ESI.
Funder
Office of International Science and Engineering
Division of Chemistry
Division of Biological Infrastructure
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP02377D
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