Solvent-free, under air selective synthesis of α-glycosides adopting glycosyl chlorides as donors
Author:
Affiliation:
1. Department of Chemical Sciences
2. University of Naples Federico II
3. I-80126 Naples
4. Italy
Abstract
A solvent-free, under air approach for the highly stereoselective synthesis of α-glycosides from glycosyl chloride donors, promoted by a triethylphosphite, tetrabutylammonium bromide, and N,N-diisopropylethylamine combination.
Funder
Università degli Studi di Napoli Federico II
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/OB/D0OB01024C
Reference50 articles.
1. Recent developments in chemical oligosaccharide synthesis
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3. 1,2-cis O-Glycosylation: Methods, Strategies, Principles
4. Stereocontrolled 1,2-cis glycosylation as the driving force of progress in synthetic carbohydrate chemistry
5. Advances in Stereoselective 1,2-cis Glycosylation using C-2 Auxiliaries
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