Electrophilic hydrophosphonylation of aldimines with alkylphosphonochloridates provides access to (<i>E</i>)-alk-1-enylphosphonamidates-Reference-Cited by-同舟云学术

Electrophilic hydrophosphonylation of aldimines with alkylphosphonochloridates provides access to (E)-alk-1-enylphosphonamidates

Published:2022 Issue:9 Volume:9 Page:2464-2470
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Fu Zhicheng¹,Lei Yelong¹,Sun Fang¹,Xu Jiaxi¹^ORCID

Affiliation:

1. State Key Laboratory of Chemical Resource Engineering, Department of Organic Chemistry, College of Chemistry, Beijing University of Chemical Technology, Beijing 100029, People's Republic of China

Abstract

Both linear and cyclic aldimines are electrophilically hydrophosphonylated with alkylphosphonochloridates in the presence of base to directly afford α,β-unsaturated (E)-alkenylphosphonamidates with excellent stereoselectivity.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D1QO01949J

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