Synthesis, structure and magnetic properties of a novel high-nuclearity oxo-carboxylate [ZnxCo13–x(μ4-O)4(O2CPh)18] cluster

Author:

Nawrocki Jan1234ORCID,Prochowicz Daniel1234ORCID,Justyniak Iwona1234ORCID,van Leusen Jan5678ORCID,Kornowicz Arkadiusz1234ORCID,Kögerler Paul5678ORCID,Lewiński Janusz12349ORCID

Affiliation:

1. Institute of Physical Chemistry

2. Polish Academy of Sciences

3. 01-224 Warsaw

4. Poland

5. Institute of Inorganic Chemistry

6. RWTH Aachen University

7. 52074 Aachen

8. Germany

9. Faculty of Chemistry

Abstract

A charge-neutral Zn(ii)/Co(ii) tridecanuclear oxocarboxylate cluster was synthesized under anaerobic conditions by the controlled hydrolysis of an alkylzinc benzoate in the presence of cobalt(ii) benzoate.

Funder

Ministerstwo Nauki i Szkolnictwa Wyższego

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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