Self-assembly of octanuclear Ln(<scp>iii</scp>)-based clusters: their large magnetocaloric effects and highly efficient conversion of CO<sub>2</sub>-Reference-Cited by-同舟云学术

Self-assembly of octanuclear Ln(iii)-based clusters: their large magnetocaloric effects and highly efficient conversion of CO₂

Published:2022 Issue:36 Volume:51 Page:13957-13969
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Wang Wen-Min¹²^ORCID,Xin Xiao-Yan¹,Qiao Na¹,Wu Zhi-Lei²³^ORCID,Li Ling⁴,Zou Ji-Yong⁴⁵^ORCID

Affiliation:

1. College of Chemistry and Materials, Taiyuan Normal University, Jinzhong, 030619, China

2. Department of Chemistry, Tianjin University, Tianjin, 300072, China

3. College of Chemistry and Environmental Science, Hebei University, Baoding, 071002, China

4. Institute of Applied Chemistry, Jiangxi Academy of Sciences, Nanchang, 330096, China

5. Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin, 300071, PR China

Abstract

A series of novel Ln8 clusters show highly heterogeneous catalytic activity for catalyzing the cycloaddition of CO2 with epoxides under mild conditions. Importantly, the Gd8 cluster exhibits a significant MCE with a larger ΔSm of 46.14 J kg−1 K−1.

Funder

National Key Research and Development Program of China

Jiangxi Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01892F

Reference108 articles.

1. Recent advances in the assembly of high-nuclearity lanthanide clusters

2. High-Nuclearity Lanthanide-Containing Clusters as Potential Molecular Magnetic Coolers