Inorganic–organic {dz2-MIIS4}⋯π-hole stacking in reverse sandwich structures: the case of cocrystals of group 10 metal dithiocarbamates with electron-deficient arenes-Reference-Cited by-同舟云学术

Inorganic–organic {d_z²-M^IIS₄}⋯π-hole stacking in reverse sandwich structures: the case of cocrystals of group 10 metal dithiocarbamates with electron-deficient arenes

Published:2022 Issue:12 Volume:9 Page:2869-2879
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Zelenkov Lev E.¹²^ORCID,Eliseeva Anastasiya A.¹^ORCID,Baykov Sergey V.¹³^ORCID,Ivanov Daniil M.¹³,Sumina Alina I.¹^ORCID,Gomila Rosa M.⁴^ORCID,Frontera Antonio⁴^ORCID,Kukushkin Vadim Yu.¹⁵^ORCID,Bokach Nadezhda A.¹³^ORCID

Affiliation:

1. Institute of Chemistry, St Petersburg State University, Universitetskaya Nab. 7/9, St Petersburg, 199034, Russian Federation

2. ITMO University, St Petersburg, 191002, Russian Federation

3. Research School of Chemistry and Applied Biomedical Sciences, Tomsk Polytechnic University, Tomsk, 634034, Russian Federation

4. Departament de Química, Universitat de les Illes Balears, Crta de Valldemoss km 7.5, 07122 Palma de Mallorca, Baleares, Spain

5. Laboratory of Crystal Engineering of Functional Materials, South Ural State University, 76, Lenin Av., Chelyabinsk, 454080, Russian Federation

Abstract

The {dz2-MIIS4} (M = Ni, Pd, Pt) moieties function as integrated five-center acceptors toward a π-hole of an electron-deficient arene furnishing the reverse sandwich structures.

Funder

Russian Foundation for Basic Research

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QI/D2QI00438K

Reference63 articles.

1. Not Only Hydrogen Bonds: Other Noncovalent Interactions

2. Noncovalent Interactions in Organometallic Chemistry: From Cohesion to Reactivity, a New Chapter