Cleavable coumarin-based oxime esters with terminal heterocyclic moieties: photobleachable initiators for deep photocuring under visible LED light irradiation

Author:

Qiu Wanwan12345,Li Mengqi56728,Yang Yinan56728,Li Zhiquan12345ORCID,Dietliker Kurt910111213ORCID

Affiliation:

1. International Research Center for Photoresponsive Molecules and Materials

2. Jiangnan University

3. Wuxi

4. P. R. China

5. Key Laboratory of Synthetic and Biological Colloids

6. Ministry of Education

7. School of Chemical and Material Engineering

8. Wuxi 214122

9. Department of Chemistry and Applied Biosciences

10. Laboratory of Inorganic Chemistry

11. ETH Zürich

12. 8093 Zürich

13. Switzerland

Abstract

Oxime ester photoinitiators with terminal heterocyclic moieties can efficiently initiate acrylate and thiol–ene photopolymerization under 450 nm LED light irradiation to prepare materials of thickness up to 10 mm.

Funder

Natural Science Foundation of Jiangsu Province

National Natural Science Foundation of China

Ministry of Education of the People's Republic of China

State Administration of Foreign Experts Affairs

Higher Education Discipline Innovation Project

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

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