How important is roaming in the photodegradation of nitrobenzene?-Reference-Cited by-同舟云学术

How important is roaming in the photodegradation of nitrobenzene?

Published:2020 Issue:28 Volume:22 Page:15945-15952
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Giussani Angelo¹²³⁴^ORCID,Worth Graham A.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University College London

3. London WC1H 0AJ

4. UK

Abstract

Three pathways have been found for the formation of NO from nitrobenzene photodegradation that lead to either low or high translational energy, with a roaming mechanism involved at high excitation energies.

Funder

European Commission

Universitat de València

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP02077J

Reference43 articles.

1. Kinetics and mechanisms of thermal decomposition of nitroaromatic explosives

2. Fine Spatiotemporal Control of Nitric Oxide Release by Infrared Pulse-Laser Irradiation of a Photolabile Donor

3. Singlet Excited-State Dynamics of Nitropolycyclic Aromatic Hydrocarbons: Direct Measurements by Femtosecond Fluorescence Up-Conversion

4. Ultrafast Intersystem Crossing in 1-Nitronaphthalene. An Experimental and Computational Study

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