Exploring Cu/Al cluster growth and reactivity: from embryonic building blocks to intermetalloid, open-shell superatoms-Reference-Cited by-同舟云学术

Exploring Cu/Al cluster growth and reactivity: from embryonic building blocks to intermetalloid, open-shell superatoms

Published:2021 Issue:19 Volume:12 Page:6588-6599
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Schütz Max¹²³⁴⁵,Gemel Christian¹²³⁴⁵,Muhr Maximilian¹²³⁴⁵^ORCID,Jandl Christian⁵²³⁴,Kahlal Samia⁶⁷⁸⁹¹⁰,Saillard Jean-Yves⁶⁷⁸⁹¹⁰,Fischer Roland A.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Technical University Munich

3. D-85748 Garching

4. Germany

5. Catalysis Research Centre

6. Univ Rennes

7. CNRS

8. ISCR-UMR 6226

9. F-35000 Rennes

10. France

Abstract

Cu/Al cluster growth reactions leading to open- and closed-shell superatoms are investigated. Therein, LIFDI-MS is presented as a powerful technique for the in situ detection of cluster identities and reactivity patterns.

Funder

Grand Équipement National De Calcul Intensif

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC00268F

Reference61 articles.

1. The Intermetalloid Cluster [(Cp*AlCu)6H4], Embedding a Cu6Core Inside an Octahedral Al6Shell: Molecular Models of Hume-Rothery Nanophases

2. The Mackay-Type Cluster [Cu43Al12](Cp*)12: Open-Shell 67-Electron Superatom with Emerging Metal-Like Electronic Structure