Decisive role of non-rare earth metals in high-regioselectivity addition of μ3-carbido clusterfullerene

Author:

Chen Muqing12ORCID,Zhao Yaoxiao34,Jin Fei2,Li Mengyang3ORCID,Guan Runnan2,Xin Jinpeng2,Yao Yang-Rong2,Zhao Xiang3ORCID,Wang Guan-Wu5ORCID,Zhang Qianyan6ORCID,Xie Su-Yuan6,Yang Shangfeng2ORCID

Affiliation:

1. School of Environment and Civil Engineering, Dongguan University of Technology, Dongguan, Guangdong 523808, China

2. Hefei National Laboratory for Physical Sciences at Microscale, Key Laboratory of Materials for Energy Conversion, Chinese Academy of Sciences, Department of Materials Science and Engineering, Synergetic Innovation Center of Quantum Information & Quantum Physics, University of Science and Technology of China, Hefei 230026, China

3. Institute of Molecular Science & Applied Chemistry, School of Chemistry, Xi'an Jiaotong University, Xi'an 710049, China

4. School of materials science and chemical engineering, Xi'an Technological University, Xi'an 710021, China

5. Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Soft Matter Chemistry, and Department of Chemistry, University of Science and Technology of China, Hefei 230026, China

6. State Key Lab for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

Abstract

The reaction of μ3-CCF Dy2TiC@Ih-C80 with AdN2 affords only one [6,6]-open monoadduct along with the addition sites adjacent to the Ti4+ ion instead of the two Dy3+ ions, revealing the decisive role of the non-rare earth metal Ti(IV).

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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