Valence shell threshold photoelectron spectroscopy of C3Hx (x = 0

Valence shell threshold photoelectron spectroscopy of C3Hx (x = 0–3)

Published:2018 Issue:13 Volume:20 Page:8707-8718
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Garcia Gustavo A.¹²³⁴^ORCID,Gans Bérenger⁵⁶⁴,Krüger Julia¹²³⁴,Holzmeier Fabian¹²³⁴⁷,Röder Anja¹²³⁴,Lopes Allan⁸⁹¹⁰¹¹¹²,Fittschen Christa¹³¹⁴⁴^ORCID,Alcaraz Christian⁸⁹¹⁰¹¹¹²^ORCID,Loison Jean-Christophe¹⁵¹⁶¹⁷⁴^ORCID

Affiliation:

1. Synchrotron SOLEIL

2. L'Orme des Merisiers

3. Gif sur Yvette

4. France

5. ISMO

6. Orsay

7. Laboratoire de Chimie Physique d'Orsay

8. CNRS – Université Paris-Sud et Paris-Saclay

9. Laboratoire de Chimie Physique

10. UMR 8000

11. Centre Universitaire Paris-Sud

12. 91405 Orsay

13. University Lille 1

14. Villeneuve d'Ascq

15. Université Bordeaux

16. ISM

17. Talence

Abstract

We present the photoelectron spectra of C₃H_x (x = 0–3) formed in a microwave discharge flow-tube reactor by consecutive H abstractions from C₃H₄ (C₃H_x + F → C₃H_x−1 + HF (x = 1–4)), but also from F + CH₄ schemes by secondary reactions.