A Raman spectroscopic study of the carbon deposition mechanism on Ni/CGO electrodes during CO/CO2 electrolysis-Reference-Cited by-同舟云学术

A Raman spectroscopic study of the carbon deposition mechanism on Ni/CGO electrodes during CO/CO2 electrolysis

Published:2014 Issue:26 Volume:16 Page:13063-13068
ISSN:1463-9076
Container-title:Phys. Chem. Chem. Phys.
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Duboviks V.¹²³,Maher R. C.⁴²³,Kishimoto M.¹²³,Cohen L. F.⁴²³,Brandon N. P.¹²³,Offer G. J.⁵²³

Affiliation:

1. Department of Earth Science and Engineering

2. Imperial College

3. London SW7 2BP, UK

4. Department of Physics

5. Department of Mechanical Engineering

Abstract

In situ and ex situ Raman analyses of porous Ni/CGO electrodes reveal differences in the amount, location and type of carbon formed during CO/CO₂ electrolysis. The majority of the carbon forms in the region of the anode, which lies in the range of ca. 4 micrometers from the electrode–electrolyte interface.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CP/C4CP01503G

Reference59 articles.

1. Energy conversion via solid oxide electrolyte electrochemical cells at high temperatures

2. Syngas production via high-temperature steam/CO2 co-electrolysis: an economic assessment

3. Hydrogen and synthetic fuel production from renewable energy sources

4. Syngas Production via High-Temperature Coelectrolysis of Steam and Carbon Dioxide

5. Syngas Production By Coelectrolysis of CO2/H2O: The Basis for a Renewable Energy Cycle

Cited by 51 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Superior syngas product control of La(Sr)Fe(Mn)O3 perovskite in high-temperature CO2/H2O co-electrolysis;Applied Catalysis B: Environment and Energy;2024-11

2. Sr(Ti0·3Fe0.7)O3−δ-based perovskite with in-situ exsolved Fe–Ru nanoparticles: A highly stable fuel electrode material for solid oxide electrochemical cells with efficient electrocatalytic CO2 reduction ability and preferential selectivity;Journal of Power Sources;2024-09

3. Active Cu and Fe Nanoparticles Codecorated Ruddlesden–Popper‐Type Perovskite as Solid Oxide Electrolysis Cells Cathode for CO₂ Splitting;ENERGY & ENVIRONMENTAL MATERIALS;2024-04-16

4. Gadolinium Doped Ceria as Nickel–Free Fuel Electrode in High Temperature CO₂‐Electrolysis;ChemElectroChem;2024-02-21

5. Conversion of CO2 through solid oxide co-electrolysis cell with cobalt-free fuel electrode;Fuel;2023-12