N-heterocyclic nitrenium charge transfer catalysis <i>via</i> inner-sphere electron transfer in concert with halogen-atom dissociation-Reference-Cited by-同舟云学术

N-heterocyclic nitrenium charge transfer catalysis via inner-sphere electron transfer in concert with halogen-atom dissociation

Published:2024 Issue:3 Volume:11 Page:673-683
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhang Chao-Shen¹,Fang Chang-Zhen¹,Yi Liang²,Zhu Chen²^ORCID,Wang Zhi-Xiang¹³^ORCID,Chen Xiang-Yu¹³^ORCID,Rueping Magnus²^ORCID

Affiliation:

1. School of Chemical Sciences, University of Chinese Academy of Sciences (UCAS), Beijing 100049, China

2. KAUST Catalysis Center (KCC), King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia

3. Binzhou Institute of Technology, Weiqiao-UCAS Science and Technology Park, Binzhou, Shandong Province 256606, China

Abstract

We report an efficient and versatile catalytic N-heterocyclic nitrenium charge transfer complex strategy for the single-electron reduction of chloroform, resulting in the generation of the dichloromethyl radical for use in various transformations.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

University of Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D3QO01779F

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