Preparation of octahydro- and tetrahydro-[1,10]phenanthroline zirconium and hafnium complexes for olefin polymerization-Reference-Cited by-同舟云学术

Preparation of octahydro- and tetrahydro-[1,10]phenanthroline zirconium and hafnium complexes for olefin polymerization

Published:2015 Issue:8 Volume:44 Page:3845-3855
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Hwang Eun Yeong¹²³⁴,Park Geun Ho¹²³⁴,Lee Chun Sun¹²³⁴,Kang Yi Young⁵⁶⁷⁸,Lee Junseong⁵⁶⁷⁸,Lee Bun Yeoul¹²³⁴

Affiliation:

1. Department of Molecular Science and Technology

2. Ajou University

3. Suwon 443-749

4. South Korea

5. Department of Chemistry

6. Chonnam National University

7. Gwangju 500-757

8. Korea

Abstract

A zirconium complex with an unusual binding mode was constructed from octahydro[1,10]phenanthroline, which is a potent catalyst for the production of wax-like low-molecular weight polyethylene (M_n: ∼5000).

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03683B

Reference51 articles.

1. Discovery of Methylaluminoxane as Cocatalyst for Olefin Polymerization

2. 1,1-Olefin-bridged bis-(2-indenyl) metallocenes of titanium and zirconium

3. Polymerization Behavior ofC1-Symmetric Metallocenes (M = Zr, Hf): From Ultrahigh Molecular Weight Elastic Polypropylene to Useful Macromonomers

4. 5-Methoxy-Substituted Zirconium Bis-indenyl ansa-Complexes: Synthesis, Structure, and Catalytic Activity in the Polymerization and Copolymerization of Alkenes

5. Stereoengineering of Poly(1,3-methylenecyclohexane) via Two-State Living Coordination Polymerization of 1,6-Heptadiene

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