Kinetico-mechanistic studies of substitution reactions on cross-bridged cyclen CoIII complexes with nucleosides and nucleotides-Reference-Cited by-同舟云学术

Kinetico-mechanistic studies of substitution reactions on cross-bridged cyclen CoIII complexes with nucleosides and nucleotides

Published:2015 Issue:42 Volume:44 Page:18643-18655
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Vázquez Marta¹²³⁴,Font-Bardia Mercè⁵⁶²⁷⁴,Martínez Manuel¹²³⁴^ORCID

Affiliation:

1. Departament de Química Inorgànica

2. Universitat de Barcelona

3. E-08028 Barcelona

4. Spain

5. Unitat de Difracció de RX

6. Centres Científics i Tecnològics de la Universitat de Barcelona (CCiTUB)

7. 08028-Barcelona

Abstract

Substitution reactions on [Co{(μ-ET)cyclen)(H₂O)₂]³⁺ are dominated by the presence of its mono-hydroxo bridged dimeric form, which coordinates to different donors of nucleosides and nucleotides depending on an outer-sphere association.

Funder

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01816A

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