Synthesis of 9-borafluorene analogues featuring a three-dimensional 1,1′-bis(o-carborane) backbone-Reference-Cited by-同舟云学术

Synthesis of 9-borafluorene analogues featuring a three-dimensional 1,1′-bis(o-carborane) backbone

Published:2019 Issue:20 Volume:55 Page:2892-2895
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Yruegas Sam¹²³⁴,Axtell Jonathan C.¹⁵⁶⁴^ORCID,Kirlikovali Kent O.¹⁵⁶⁴^ORCID,Spokoyny Alexander M.¹⁵⁶⁴⁷^ORCID,Martin Caleb D.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. Baylor University

3. Waco

4. USA

5. University of California, Los Angeles

6. Los Angeles

7. California NanoSystems Institute (CNSI)

Abstract

The synthesis of [1,1′-bis(o-carboranyl)]boranes was achieved through the deprotonation of 1,1′-bis(o-carborane) reagents followed by salt metathesis with (ⁱPr)₂NBCl₂.

Funder

Research Corporation for Science Advancement

National Science Foundation

Welch Foundation

Alfred P. Sloan Foundation

National Institute of General Medical Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CC/C8CC10087J

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3. Spherical Aromaticity: Recent Work on Fullerenes, Polyhedral Boranes, and Related Structures

4. Potential applications of the boron cluster compounds

5. Cage C_H⋯X interactions in solid-state structures of icosahedral carboranes

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